Product ID:STATHANE 811-2 COMPONENT 1 PART A
MSDS Date:07/29/1992
FSC:9330
NIIN:00N043005
Kit Part:Y
MSDS Number: BRRBY

EXPANDED RUBBER & PLASTIC CORP

14000 S WESTERN AVE
GARDENA, CA 90249
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 213-321-4360

Cage: 25598

EXPANDED RUBBER AND PLASTIC CORP

GARDENA, CA 90249-3008 US

Telephone: 310-321-4260

Cage: 25598

ISOCYANIC ACID, METHYL-M-PHENYLENE ESTER;

CAS: 26471-62-5

RTECS: NQ9490000

Fraction By Weight: 81.0%

OSHA PEL 0.005PPM;0.02 STEL

ACGIH TLV: 0.005PPM;0.02 STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

POLYESTER POLYOL

Fraction By Weight: <30%

OSHA PEL N/K

ACGIH TLV: N/K

BENZOYL CHLORIDE

CAS: 98-88-4

RTECS: DM6600000

Fraction By Weight: <15%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:VAPORS INHAL MAY CAUSE SEVERE
IRRITATION OF RESPIRATORY TRACT. PROLONGED EXPOSURE MAY CAUSE
PULMONARY EDEMA, CHRONIC LUNG IMPAIRMENT. LIQUID CONTACT CAUSES
SERIOUS SKIN AND EYE BURNS.
Explanation of Carcinogenicity:TOLUENE DIISOCYANATE:IARC MONOGRAPHS
SUPP, VOL 7,PG 56,'87:GRP 2B.ANTICIP TO BE CARCIN,NTP 6'TH ANN RPT
ON CARCIN.'91.
Effects of Overexposure:DIFFICULT, LABORED BREATHING, ASTHMA-LIKE
ATTACKS IN SENSITIVE PERSONS, SEVERE IRRITATION OF SKIN, EYE
DAMAGE, OR TDI SENSITIZATION.
Medical Cond Aggravated by Exposure:RESPIRATORY, BRONCHIAL CONDITIONS.
SKIN SENSITIVITY.

First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. GET MED ATTN.
SKIN: WASH W/PLENTY OF SOAP & WATER. REMOVE CONTAMD CLTHG. INGEST:
GIVE PLENTY OF WATER. DO NOT INDUCE VOMIT. GET MED ATTN. INHAL:
MOVE TO FRESH AIR. GIVE OXYGEN IF NEC. GET MEDATTN.

Flash Point Method:PMCC
Flash Point:260F,127C
Lower Limits:0.9%
Upper Limits:9.5%
Extinguishing Media:WATER FOG, CARBON DIOXIDE OR FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . OXIDES OF CARBON, NITROGEN, ISOCYANATE VAPS
& HCN WILL BE GENERATED.
Unusual Fire/Explosion Hazard:WATER CONTAM MATL WILL GENERATE CARBON
DIOXIDE WHICH MAY CAUSE EXPLOS RUPTURE OF CLSD CONTRS WHEN EXPOSED
TO FIRE CNDTNS. COOL DOWN CLSD CONTRS W/WATER SPRAY.

Spill Release Procedures:CLEAN UP CREW MUST WEAR FULL PROT EQUIP.
ABSORB MATL W/SAWDUST/SWEEPING COMPOUND. DECONTAM W/MIXTURE OF 90%
WATER, 8% CONCENTRATED AMMONIA, & 2% DETERGENT. SHOVEL IT INTO OPEN
TOP DRUMS & REMOVE TO WE LL VENTILATED AREA.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS IN
DRY COOL PLACES @ TEMPS BETWEEN 70-90F.
Other Precautions:PROD REACTS W/WATER & OTHER SUBSTANCES GENERATING
CARBON DIOXIDE GAS WHICH WILL CAUSE SEALED CONTRS TO EXPAND & POSS
RUPTURE. DO NOT RESEAL CONTRS IF CONTAM IS SUSPECTED. EXPOS TO VAPS
OF HOT MATL CAN BE EXTREMELY DANGEROUS.

Respiratory Protection:NIOSH/MSHA APPROVED SCBA, GAS MASKS EQUIPPED
WITH ORGANIC CARTRIDGES, MASKS WITH EXTERNAL AIR SOURCES.
Ventilation:LOCAL EXHAUST/MECHANICAL(GEN): YES. SPECIAL: TDI VAPS ARE
HVR/AIR. DESIGN EXHAUST SYSTEMS ACCORDINGLY.
Protective Gloves:CHEM RESIST RUBB/PLASTICS.
Eye Protection:CHEM SFTY GOG & FULL LNGTH FSHLD .
Other Protective Equipment:COVERALLS, BOOTS, RUBBER APRONS. EMERGENCY
EYEWASH AND DELUGE SHOWER .
Work Hygienic Practices:DO NOT EAT, DRINK/SMOKE IN WORKING AREAS. KEEP
CLOTHING CLEAN AND EQUIPMENT CLEAN @ ALL TIMES.
Supplemental Safety and Health
KEY1;T3. SOL IN H2O: REACTS WITH WATER, GENERATING CARBON DIOXIDE.

HCC:T3
Boiling Pt:B.P. Text:480F,249C
Vapor Pres:0.01@20C
Vapor Density:6
Spec Gravity:1.2(H2O=1)
Evaporation Rate & Reference:<0.01(BUTYL ACETATE=1)
Solubility in Water:SUPP DATA
Appearance and Odor:LIGHT YELLOW, MEDIUM VISCOSITY LIQUID. STRONG
PUNGENT ODOR.

Stability Indicator/Materials to Avoid:YES
BASIC COMPOUNDS, CAUSTIC SODA, TERTIARY AMINES, WATER.
Stability Condition to Avoid:TEMPERATURES ABOVE 40C FOR EXTENDED
PERIODS OF TIME.
Hazardous Decomposition Products:ISOCYANATE VAPORS, OXIDES OF CARBON
AND NITROGEN, HCN.
Conditions to Avoid Polymerization:WATER AND OTHER PRODUCTS THAT REACT
W/ ISOCYANATES.

Waste Disposal Methods:DISPOSAL OF WASTE MUST BE DONE I/A/W FEDERAL,
STATE AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.